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硫代双烯型近红外染料的制备与物性研究 被引量：3

Study on the Synthesis and Physical Properties of Nickel Dithiolenes with Alkoxynaphthyl Units
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摘要 本文设计并合成了一个长碳链的庚氧基萘硫代双烯镍络合物,其结构被完全表征。其UV-Vis、差热(TG)分析测试结果表明:该络合物呈现出良好的热稳定性;通过循环伏安法(CV)测定,结果显示该络合物具有较小的HOMO-LUMO能隙。 In the paper,a symmetric nickel bis(dithiolene)complex containing naphthyl units was designed and prepared,its structure was characterized by IR、1H-NMR and 13C-NMR.On the basis of the analysis toward its UV-Vis spectrum and thermogravimetic analysis,the good photo-thermo stability was displayed.Meanwhile,the result of Cyclic Voltammetry(CV)revealed the complex has small HOMO-LUMO gap.
作者 张拓 王依琳 刘蕊 贾敬怡 韩爱鸿 ZHANG Tuo;WANG Yi-lin;LIU Rui;JIA Jing-yi;HAN Ai-hong(College of Chemistry and Chemical Engineering,Shenyang Normal University,Shenyang 110034,Liaoning China)
机构地区 沈阳师范大学化学化工学院
出处 《染料与染色》 CAS 2019年第6期9-12,共4页 Dyestuffs and Coloration
关键词 硫代双烯镍 近红外染料 光热稳定性 受体材料 nickel bis(dithiolene) near infrared dyes photo-thermo stability acceptors
分类号 TQ618.99 [化学工程—精细化工]
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染料与染色
2019年 第6期

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