摘要
A simple and clean protocol for the synthesis of various alkyl and(hetero)aryl S-thiocarbamates was established.The usage of in situ generated hydroxide as both an oxygen source and hydrogen source as well as biomass-derived 2-methyltetrahydrofuran as a green reaction medium,the avoidance of phosphorus-containing reductant,and the generation of harmless water and nitrogen as the sideproducts have given the present method atom-economy and environmental friendliness.
A simple and clean protocol for the synthesis of various alkyl and(hetero)aryl S-thiocarbamates was established.The usage of in situ generated hydroxide as both an oxygen source and hydrogen source as well as biomass-derived 2-methyltetrahydrofuran as a green reaction medium,the avoidance of phosphorus-containing reductant,and the generation of harmless water and nitrogen as the sideproducts have given the present method atom-economy and environmental friendliness.
基金
financial support from the Hunan Provincial Natural Science Foundation of China (Nos.2019JJ50193 and 2019JJ20008)
