摘要
为了解决燃料电池阴极催化剂价格昂贵、稳定性差等问题,使用α-亚硝基-β-萘酚铜、三聚氰胺和导电碳黑通过简单的热处理制备Cu、N共掺杂的碳基催化剂(Cu-N-KB)。表征结果证实Cu、N均匀分布在碳载体中,其中铜以晶态铜粒子和非晶态的Cu-Nx两种方式存在,该催化剂高的比表面积与介孔结构确保了其大量的活性位点和快速的传质效率。该催化剂在碱性介质中表现出比商业Pt/C催化剂优异的氧还原催化性、抗甲醇性和稳定性。
In order to solve the problems of high cost and poor stability of fuel cell cathode catalysts,Cu,N co-doped carbon based catalyst(Cu-N-KB)was prepared by simple heat treatment usingα-nitroso-β-naphthol copper,melamine and conductive carbon black.The characterization results show that Cu and N are uniformly distributed in the carbon support and the copper exists in the form of crystalline copper particles and amorphous Cu-Nx.The high specific surface area and mesoporous structure of the catalyst ensure a large number of active sites and fast mass transfer efficiency.The catalyst exhibits excellent oxygen reduction catalysis,methanol resistance and stability in an alkaline medium compared to commercial Pt/C catalysts.
作者
李思佳
朱杰
郑继明
耿继业
李义兵
LI Si-Jia;ZHU Jie;ZHENG Ji-Ming;GENG Ji-Ye;LI Yi-Bing(College Material Science and Engineering,Guilin University of Technology,Guilin,Guangxi 541000,China)
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2020年第4期627-635,共9页
Chinese Journal of Inorganic Chemistry
关键词
氧气还原反应
过渡金属-氮共掺杂碳
铜粒子
oxygen reduction recation transition
metal-nitrogen co-doped
copper particles