摘要
Peripherally low symmetric substitution with electron-donating(EDG)and electron-withdrawing(EWG)substituents caused the rational modulation of geometric structure and even the electronic structure of triazasubporphyrin,the smallest 14πconjugated aza-porphyrinoids.Both structural characterization and spectroscopic investigation were discussed to provide an in-depth understanding of the relationship between peripheral push-pull substituents and SubPz core.
作者
樊宇轩
袁太艳
吕庆洋
李敏智
朱卫华
梁旭
FAN Yu-Xuan;YUAN Tai-Yan;LV Qing-Yang;LI Min-Zhi;ZHU Wei-Hua;LIANG Xu(School of Chemistry and Chemical Engineering,Jiangsu University,Zhenjiang 212013,China)
基金
Financially supported by the National Natural Science Foundation of China(No.21701058)
the Natural Science Foundation of Jiangsu province(No.BK20160499)
the State Key Laboratory of Coordination Chemistry(SKLCC1817)
the Key Laboratory of Functional Inorganic Material Chemistry(Heilongjiang University)of Ministry of Education,the China post-doc foundation(No.2018M642183)
the Lanzhou Entrepreneurial and Innovative Talents Project(2018-RC-105)
the Jiangsu University(No.17JDG035)。
