摘要
以二芳基烯丙醇与溴乙腈为原料,开发了一种可见光诱导的合成δ-酮腈的方法.控制实验的结果表明,该反应可能是通过自由基机理进行的,溴乙腈作为氰甲基自由基源参与到反应中.
A photocatalyzed method for the synthesis of δ-ketonitriles from the reaction of diaryl allyl alcohols with bromoacetonitrile is developed. The result of control experiments indicates that the reaction might proceed via a free radical mechanism and bromoacetonitrile was the source of cyanomethyl radical.
作者
杜琳琳
李铁生
Du Linlin;Li Tiesheng(Henan Key Laboratory of Chemical Biology and Organic Chemistry,Key Laboratory of Applied Chemistry of Henan Universities,College of Chemistry and Molecular Engineering,Zhengzhou University,Zhengzhou 450052)
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2020年第1期140-148,共9页
Chinese Journal of Organic Chemistry
