摘要
A new Cu(II) coordination polymer, {[Cu(1,3-BIP)(TFBDC)]·DMF}n(1,1,3-BIP is a 1,3-bis(imidazole)propane, and H2TFBDC is 2,3,5,6-tetrafluoroterephthalic acid) was prepared under solvothermal conditions and characterized by single-crystal and powder X-ray diffraction, IR spectra, thermogravimetric analyses and elemental analyses. The single-crystal X-ray diffraction reveals that metal coordination polymer 1(MCP 1) shows a two-dimensional sheet layer structure, which is further reinforced through strong intermolecular hydrogen bonding to form a 3 D supramolecular framework. Furthermore, the photocatalytic experiment result indicates the degradation ratios of methyl orange(MO) reach 83.4% within 180 minutes when MCP 1 acts as catalyst.
作者
卢久富
赵娟
赵蔡斌
于小虎
SOUMENDRA Kumar Roy
岳思羽
李丽
周科
靳玲侠
葛红光
LU Jiu-Fu;ZHAO Juan;ZHAO Cai-Bin;YU Xiao-Hu;SOUMENDRA Kumar Roy;YUE Si-Yu;LI Li;ZHOU Ke;JIN Ling-Xia;GE Hong-Guang(Shaanxi Key Laboratory of Catalysis,College of Chemical and Environment Science,Shaanxi University of Technology,Hanzhong 723001,China)
基金
Supported by the team of syngas catalytic conversion of Shaanxi University of Technology,the National Natural Science Foundation of China(No.21373132,21603133)
Key scientific research project of education department of Shaanxi province(18JS023)
Shaanxi provincial science and technology department project(2018JM2043,2019JQ149,2019JM471)
the Science Foundation of Shaanxi University of Technology(No.SLGQD2017-14)。
