摘要
The ZSM-5 zeolite with flower-shaped crystallites(marked as ZFS)was synthesized through the hydrothermal preparation method.The properties of ZFS as a supporting material have been investigated in comparison with the traditional ZSM-5 zeolite.The prepared samples were characterized by XRD,N2 adsorption-desorption,TEM,NH3-TPD,XRF,and XPS techniques.The results showed that the formation of the flower-shaped crystallites directly influenced the physicochemical properties of ZFS material.In ZFS,the pore structure was changed,the acid content was decreased,and the surface properties were promoted.Besides,in the PtSnNa/ZFS catalyst,the amount of oxidized Sn species was remarkably increased and the dispersion of Pt was relatively improved.Meanwhile,due to these modifications,the capacity of the catalyst supported on ZFS to accommodate coke was greatly improved and the coke deposits on PtSnNa/ZFS were migrated from active metals to the support.Furthermore,as expected,the catalytic performance of the PtSnNa/ZFS catalyst for propane dehydrogenation to propylene and the stability of catalyst were significantly improved.
基金
This work was funded by the National Nature Science Foundation of China(51673040)
the Natural Science Foundation of Jiangsu Province(BK20180366,BK20171357)
the Fundamental Research Funds for the Central Universities(No.3207048418)
the Fundamental Research Funds for Central Universities(2242018k30008)
the Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions(1107047002)
the Fund Project for Transformation of Scientific and Technological Achievements of Jiangsu(BA2018045)
the Prospective Joint Research Project of Jiangsu Province(BY2016076-01)
the Opening Project of Guangxi Key Laboratory of Clean Pulp&Papermaking and Pollution Control(KF201605)
the Scientific Innovation Research Foundation of College Graduates in Jiangsu Province(KYLX16_0266).
