摘要
锂二氧化碳电池通过捕获、转化二氧化碳为储能物质,既可以减少二氧化碳排放量又可以作为创新的储能装置,引起了研究者们的广泛关注。但是,目前锂二氧化碳电池还存在着放电容量低,循环性能差等缺点。本文通过对天然松木碳化制备无粘结剂自支撑阴极材料用于锂二氧化碳电池,得益于生物质衍生碳的多孔道特性和自支撑结构,极大地提高了锂二氧化碳电池的放电容量(4.12 mAh·cm^-2)和循环性能(55圈)。这种利用天然生物质衍生碳作为自支撑阴极的方法为提高锂二氧化碳电池性能提供了一种新的思路。
By capturing and converting carbon dioxide into energy storage materials,lithium carbon dioxide battery can reduce carbon dioxide emissions and serve as an innovative energy storage device,which has attracted extensive attention from researchers.However,the current lithium carbon dioxide battery still has a low discharge capacity,poor cycle performance and other shortcomings.In this paper,a non-binder self-supporting cathode material for lithium carbon dioxide battery was prepared by carbonizing natural pine wood,the discharge capacity(4.12 mAh·cm^-2)and cycle performance(55 laps)of lithium carbon dioxide battery are greatly improved thanks to the multi-channel characteristics and self-supporting structure of biomass derived carbon.This method of using carbon derived from natural biomass as self-supporting cathode provides a new idea for improving the performance of lithium carbon dioxide batteries.
作者
张英杰
王朕
吴刚
董鹏
曾晓苑
李雪
ZHANG Yingjie;WANG Zhen;WU Gang;DONG Peng;ZENG Xiaoyuan;LI Xue(Key Laboratory of Advanced Battery Materials of Yunnan Province,National and Local Joint Engineering Laboratory for Lithium-ion Batteries and Materials Preparation Technology,School of Materials Science and Engineering,Kunming University of Science and Technology,Kunming 650093,China)
出处
《人工晶体学报》
EI
CAS
北大核心
2020年第4期646-650,共5页
Journal of Synthetic Crystals
基金
国家自然科学基金(51904130,21965017)
云南省应用基础研究计划(2017FD091,2017FB085)。
关键词
生物质衍生
多孔碳
空气阴极
锂二氧化碳电池
biomass derived
porous carbon
air cathode
lithium carbon dioxide battery