摘要
MXene是一类通过选择性蚀刻MAX相材料制得的金属碳化物和碳氮化物的二维晶体。得益于独特的二维结构与丰富可调的组分,MXene在电催化领域展现出了非常好的应用前景。主要介绍了MXene的结构与性质,以及以Ti3C2为代表的MXene的制备方法,讨论了MXene在CO氧化、储氢材料中的脱氢、氧还原反应、析氧反应、析氢反应、固氮反应等领域中的应用,并分析展望MXene在电催化领域的应用前景和未来的研究方向。
MXene,a large family of novel 2D transition metal carbides(nitrides),which is obtained from selectively etching of MAX ceramics,are candidates for electrocatalysis.Thanks to its unique two-dimensional structure and abundant adjustable components,MXene has shown a promising application prospect in the field of electrocatalysis.The structure and properties of MXene and the preparation of MXene represented by Ti3C2 were introduced.The applications of MXene in CO oxidation,dehydrogenation,oxygen reduction,oxygen evolution,hydrogen evolution and nitrogen fixation of hydrogen storage materials were discussed.Finally,the future outlook of MXene in electrocatalysis was analyzed in-depth.
作者
王一博
李腾飞
李明明
顾佳俊
WANG Yi-bo;LI Teng-fei;LI Ming-ming;GU Jia-jun(State Key Laboratory of Metal Matrix Composites,School of Materials Science and Engineering,Shanghai Jiao Tong University,Shanghai 200240,China)
出处
《电源技术》
CAS
北大核心
2020年第5期781-784,790,共5页
Chinese Journal of Power Sources
基金
国家重点研发计划(2017YFB0406100)
国家自然科学基金(51672175)
国际科技合作计划(2017YFE0113000)
上海市科学技术委员会项目(16520710900)。