期刊文献+

甲基二氯化膦封闭厂房泄漏后处理措施研究

Study on the Treatment of Leakage in the Closed Workshop of Methyldichlorophosphine
下载PDF
导出
摘要 甲基二氯化膦作为一种农药中间体化学性质极不稳定,暴露在空气中会冒烟、自燃,甚至爆炸。为降低环境对介质影响以及有毒有害介质泄漏扩散采用封闭厂房设计,但封闭后事故通风量太大,导致后续废气处理困难。本文结合甲基二氯化膦的物性以及封闭厂房的设计,研究了一套解决其泄漏后的处理措施。 Methyldichlorophosphine,as an intermediate of pesticide,is very unstable in chemical properties.When exposed to the air,it will smoke,self-ignite and even explode.In order to reduce the impact of the environment on the medium and the leakage and diffusion of toxic and harmful medium,the closed workshop is designed.However,after the closure,the accident ventilation is too large,which makes the subsequent waste gas treatment difficult.In this paper,combined with the physical properties of Methyldichlorophosphine and the design of closed workshop,a set of treatment measures to solve the leakage is studied.
作者 巩鑫贤 Gong Xinxian(CNOOC Petrochemical Engineering Co.,Ltd.,Jinan 250101,China)
出处 《山东化工》 CAS 2020年第9期124-125,127,共3页 Shandong Chemical Industry
关键词 甲基二氯化膦 封闭厂房 泄漏处理 有毒有害 methyldichlorophosphine closed workshop treatment of leakage toxic and harmful
  • 相关文献

参考文献3

二级参考文献18

  • 1汪建宇.智能防火卷闸门[J].中国仪器仪表,2006(10):76-77. 被引量:5
  • 2Soroka M A simple preparation of methylphosphonous dichloride[J]. Synthesis, ,1977, ,1977(07): 450-450.
  • 3Friedrich W. Hoffmann, Thomas C. Simmons, Louis J. Glunz. Organic Phosphorus Compounds. 1. The Conversion of the Chloroaluminate Complexes, [RPCI3][A1CI4]. to Alkyl Alkylphosphonochloridates and Dialkyl Alkylphosphonates[J]. Journal of the American chemical society, ,1957, 79(13): 3570-3575.
  • 4US3, 024, ,278[P1. ,1959.
  • 5USSR221, 697[P]. ,1967.
  • 6USSR 362, 026[P]. ,1970.
  • 7Pianfetti J A, Quin L D. Formation of phosphonous dichloridesby alkylation of phosphorus trichloride with methane or ethanel[J]. Journal of American ChemiealSociety, ,1962, 84: 851-854.
  • 8Ulmer H E, Drogenwe L C, Maier L. A preparative method for alkylhalo-phosphines[J]. Joumal of Inorganic and Nuclear Chemistry, ,1961,20: 82-84.
  • 9USSR,279, 617[P]. ,1964.
  • 10崔学军,朱翠肖,马志宏,王红,林进.钙钛矿型催化剂La_(0.7)K_(0.3)CoO_3催化合成甲基二氯化膦[J].河北师范大学学报(自然科学版),2009,33(2):210-213. 被引量:3

共引文献3

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部