紫外辅助缠绕玻璃纤维增强树脂基复合材料的制备和力学性能研究

Preparation and Mechanical Properties of UV⁃Assisted Filament Winding Glass Fiber Reinforced Polymer⁃Matrix Composite

本文研究了紫外辅助固化玻璃纤维增强复合材料缠绕成型环形构件的制备过程和力学性能。基于光线追踪法量化了树脂浇注体中的紫外穿透能力,并制备了紫外辅助固化的光-热双重固化典型样件,研究了缠绕速度和热固化引发剂的浓度对缠绕制件的纤维体积分数和力学性能的影响。纤维体积分数和构件的失效分析分别采用图像法、力学性能测试和扫描电镜测试。光线追踪结果表明:紫外光能够穿透一层纤维束的厚度且背光面透过的紫外能量足以快速引发固化;试验结果表明:本文制备的紫外辅助固化复合材料环形样件与热固化试件相比均能满足飞轮转子对性能的要求。

This paper studied the preparation and mechanical properties of glass fiber reinforced polymer-matrix composite rings prepared by filament winding assisted by ultraviolet(UV)curing.A ray-tracing method was used to calculate the penetration ability of UV light in the resin casting,and then a typical composite ring with dual⁃curing characteristics was prepared by UV-assisted curing.The effects of winding speed and thermal initiator concentration on the distribution of fiber fraction and mechanical properties were studied.Microscopic morphology was used for the observation of the differences in fiber volume fraction.Mechanical properties tests and scanning electron micrographs were performed to investigate the failure and damage mechanisms of the composite ring samples.The ray tracing results indicate that the UV light can pass through a single yarn thickness and the energy transmitted is sufficient to cure the back side quickly.The experimental results show that the mechanical properties of the composite ring prepared in this paper are comparable to those of the heat-cured samples,which is sufficient to meet the requirements of the flywheel.