摘要
总结了近年来可见光促进苯及其衍生物去芳构化反应的研究进展,主要分为基态与激发态化学两方面,并对该领域的发展前景进行了展望.
Benzene rings are widely found in petrochemicals,which are cheap and readily available.Compared with other(hetero)aromatic rings,the dearomatization of benzene rings is more challenging as benzene is more stable.On the other hand,visible-light photocatalysis has experienced rapid development since last decade.Upon visible-light irradiation,highly active intermediates are formed to break aromatic stability and to construct three-dimensional molecules from flat compounds.In this review,recent examples on visible-light-promoted dearomatization of benzene and derivatives are summarized,which can be divided into two main categories:ground-state chemistry and excited-state chemistry.The perspective for future development of this field is also discussed.
作者
朱敏
张霄
游书力
ZHU Min;ZHANG Xiao;YOU Shuli(State Key Laboratory of Organometallic Chemistry,Shanghai Institute of Organic Chemistry,University of Chinese Academy of Sciences,Shanghai 200032,China;School of Physical Science and Technology,ShanghaiTech University,Shanghai 201210,China)
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
2020年第7期1407-1414,共8页
Chemical Journal of Chinese Universities
基金
国家自然科学基金(批准号:21821002,21801248)
上海市扬帆计划(批准号:18YF1428900)资助.
关键词
苯
去芳构化
能量转移
单电子转移
可见光
Benzene
Dearomatization
Energy transfer
Single electron transfer
Visible light
