催化不对称碳硼成键反应研究进展

Recent Advances of Catalytic Asymmetric C-B Bond Forming Reactions

从不对称催化的角度总结了近年来碳硼成键反应的研究进展,评述了这些反应各自的特点,并对其未来研究进行了展望.

Organoboron compounds are of particular importance in the fields of synthesis,pharmaceutical and material sciences.With retention of the absolute configuration,a boryl group can be easily transformed into another functional group,which make chiral organoborons versatile reagents in synthetic chemistry.On the other side,chiral organoborons can serve as drugs or bioactive molecules and applied for the diagnosis and treatment of many diseases.Given these functions,methods for the synthesis of chiral organoboron compounds are intensively investigated in the field of organic synthesis.Herein,we reviewed the recent progresses on the catalytic asymmetric C-B bond forming reactions.