摘要
We reveal here a visible-light promoted phosphorylation of 2-isocyanoaryl thioethers for the first time with concomita nt C(sp3)-S bond cleavage and imidoyl C-S fo rmation.Additionally,this method features the use of 3 mol%organic dye Rose Bengal as the photocatalyst without external transition-metal or peroxide oxidants,and provides a novel and environmentally friendly approach for the preparation of a variety of 2-phosphoryl benzothiazoles in moderate to good yields.
基金
financial support from the Natural Science Foundation of the Jiangsu Higher Education Institutions of China(No.19KJB150020)
Basic Research Project(Natural Science Foundation for Young Scholars)of Jiangsu Province,China(No.BK20170489,BK20180916)
High Level Introduction of Talent Research Start-up Foundation of YZU(No.137011457)
China Postdoctoral Science Foundation(No.2019T120471)。
