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Two N-donor Auxiliary Ligands Mediated Zn(Ⅱ) Coordination Polymers Incorporating 5-Nitro-1,2,3-benzenetricarboxylate Ligand: Syntheses, Crystal Structures, and Luminescent Properties

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摘要 Two N-donor auxiliary ligands mediated Zn(Ⅱ) coordination polymers, namely, {[Zn(Hnbta)-(bimm)](3H2O)}n(1) and {[Zn1.5(nbta)(pyim)(H2O)](2H2O)}n(2)(H3nbta = 5-nitro-1,2,3-benzenetricarboxylic acid, bimm = bis(imidazol-1-yl)methane and pyim = N-(4-pyridylmethyl)imidazole), have been prepared by the hydrothermal reaction. Their structures were determined by single-crystal X-ray diffraction analysis, elemental analyses and infrared spectra. Compound 1 possesses a one-dimensional(1D) chain structure, while compound 2 features a two-dimensional(2D) network. In addition, they both exhibit high thermal stabilities and photoluminescent properties in the solid, and can be explored as potential luminescent materials.
作者 ZHANG Tian ZHAO Yi-Jing QIN Qiu-Pei 张甜;赵一静;秦秋沛(College of Chemistry and Chemical Engineering, and Henan Key Laboratory of Functionoriented Porous Materials, Luoyang Normal University,Luoyang 471934,China)
机构地区 College of Chemistry and Chemical Engineering
出处 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2020年第6期1051-1056,共6页 结构化学（英文）
基金 supported by the grants from Luoyang normal university。
关键词 coordination polymer 5-nitro-l 2 3-benzenetricarboxylic acid bis(imidazoI-l-yl)methane N-(4-pyridylmethyl)imidazole photoluminescent properties
分类号 O641.4 [理学—物理化学]
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Chinese Journal of Structural Chemistry
2020年 第6期

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