摘要
介绍了以六氯丁二烯、含氟烯烃、氟氯烯烃和含氟烷烃为原料制备六氟-2-丁炔的方法;并讨论了六氟-2-丁炔制备顺-1,1,1,4,4,4-六氟-2-丁烯和1,1,1,4,4,4-六氟丁烷,及在环保型绝缘气体、含双三氟甲基堆块化合物、耐腐蚀性新型材料、聚合催化剂、医药及农药等含氟精细化学品的应用研究进展。
Preparation method of hexafluoro-2-butyne from hexachlorobutadiene, fluoroolefins, fluorochloroolefins and fluoroalkanes was introduced. Z-HFO-1336 and HFC-356 are prepared from hexafluoro-2-butyne. Application research progress of hexafluoro-2-butyne was discussed in insulating gas, trifluoromethyl bulk compound, corrosive materials, polymerization catalysts, medicines, pesticides and fluorine-containing fine chemicals.
作者
马超峰
李玲
金佳敏
刘武灿
石能富
缪光武
肖新宝
MA Chaofeng;LI Ling;JIN Jiamin;LIU Wucan;SHI Nengfu;MIAO Guangwu;XIAO Xinbao(State Key Laboratory of Fluorinated Greenhouse Gases Replacement and Control Treatment,The National ODS Substitutes Engineering&Technology Research Center,Zhejiang Chemical Industry Research Institute,Hangzhou 310023,China)
出处
《有机氟工业》
CAS
2020年第2期48-52,共5页
Organo-Fluorine Industry
关键词
六氟-2-丁炔
调聚
氟化
脱氯
hexafluoro-2-butyne
telomerization
fluorination
dechlorination