Experimental study of phase equilibria on Co-Fe-rich side of Co-Al-Fe system

Despite various studies on Co-Al-Fe ternary system, its phase equilibria are still in doubt. Phase equilibria, magnetic transition and bcc_A2/bcc_B2 order-disorder transformation at the Co-Fe-rich side of the Co-Al-Fe alloys were carefully investigated by means of electron probe microanalysis (EPMA), X-ray diffraction (XRD) and differential scanning calo-rimetry. The equilibrium phases and their compositions were determined by 18 alloy samples annealed at 900, 1000, 1100 and 1200℃ for 528, 336, 168 and 96h, respectively, followed by quenching. However, by adopting the above traditional method, bcc_A2 and fcc_A1 phases are difficult to be distinguished through XRD analysis at room temperature due to the martensitic transformation of fcc_A1 phase during quenching. For this reason, high-temperature insitu XRD technique was utilized to correctly establish the phase relationships among bcc_A2, bcc_B2 and fcc_A1 phases. The phase transformation between bcc_A2 and B2 phases was determined to be second order instead of first order at temperatures higher than 900℃. The equilibrium phases and compositions were further confirmed by fabricating 16 diffusion couples together with EPMA. Meanwhile, using three-dimensional differential scanning calorimetry method, bcc_A2/B2 and ferro-/paramagnetic transi-tions were determined with high accuracy.