摘要
本文以邻叔丁基苯酚为起始原料,经溴化、偶连和甲酰化三步反应制得联苯型双水杨醛化合物,再与2,6-二甲基苯胺发生席夫碱反应得到双水杨醛亚胺型席夫碱配体,探讨了合成条件对制备过程的影响并通过1H NMR、13 C NMR和FT-IR等手段对所得化合物进行表征。
In this paper,the biphenylsalicylaldehyde compound was synthesized with o-tert-butylphenolas the starting material through three steps including bromination,coupling and formylation,which then reacted with 2,6-dimethylaniline bythe Schiff basereaction to obtain biphenyl salicylaldiminebidentate Schiff base ligand.The influence of reaction conditions on the preparation process were discussed.The obtained compounds were characterized by 1H NMR,13 C NMR and FT-IR.
作者
杨子锋
秦亚雯
李建
蒙祥
谢光勇
Yang Zifeng;Qin Yawen;Li Jian;Meng Xiang;Xie Guangyong(Key Laboratory of Catalysis and Energy Materials Chemistry of Ministry of Education&Hubei Key Laboratory of Catalysis and Materials Science,South-Central University for Nationalities,Wuhan 430074,China)
出处
《山东化工》
CAS
2020年第14期1-2,6,共3页
Shandong Chemical Industry
基金
国家自然科学基金项目(21172269)
江汉大学光电化学材料与器件教育部重点实验室开放基金(JDGD-201809)。
关键词
席夫碱
双齿配体
水杨醛
Schiff base
bidentate ligand
salicylaldehyde
