摘要
理论计算乙酸乙酯与碳酸钠溶液作用的反应限度,设计实验并证实乙酸乙酯与碳酸钠溶液可以反应得到乙酸钠和碳酸氢钠。通过对乙酸乙酯碱性水解机理的解读、讨论、分析,发现该反应速率极小,是因为碳酸钠溶液的强极性,导致乙酸乙酯与碳酸钠溶液相互作用的接触面积显著减小所致。
In this paper, the mechanism for alkaline hydrolysis of ethyl acetate was analyzed, the limit of reaction for the interaction between ethyl acetate and sodium carbonate solution was calculated theoretically, and the fact that sodium acetate and sodium bicarbonate could be obtained by the reaction of ethyl acetate with sodium carbonate solution was exampled and verified. And this paper analyzed that the significant decrease of contact area of the interaction between ethyl acetate and sodium carbonate solution was caused by the strong polarity of sodium carbonate solution, which resulted in the smallest rate of reaction.
作者
王飞
吴文中
WANG Fei;WU Wen-Zhong(Yuezhou High School,Shaoxing 312075,China)
出处
《化学教育(中英文)》
CAS
北大核心
2020年第15期88-91,共4页
Chinese Journal of Chemical Education
关键词
饱和碳酸钠溶液
乙酸乙酯
反应限度
反应速率
接触面积
saturated sodium carbonate solution
ethyl acetate
limit of reaction
rate of reaction
contact area