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红外光谱在传统年画红蓝色料分析中的应用研究 被引量:8

Analysis of red/blue pigments and dyes in traditional folk paintings using FTIR spectrometry
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摘要 年画是中国特有的民间艺术形式。本研究介绍了传统年画印制所用红蓝色料的发展历史,选取15种中国古代与近现代常用红蓝色料进行红外光谱分析,并归纳总结了标准样品的化学结构与红外谱图特征。在此基础上,利用衰减全反射傅里叶变换红外光谱仪对三幅清末民初时期的传统年画开展无损检测。结果显示三幅年画的红蓝色料均为合成颜料或染料,包括酸性大红G、酸性墨水蓝G、普鲁士蓝等。本研究扩展了红外光谱在书画文物分析检测中的应用范围,为传统年画色料的无损鉴定提供科学依据。 Traditional folk paintings,used for the celebration of Chinese New Year,are a unique form of Chinese folk art.We introduce the history of red/blue pigments and dyes used for the printing of traditional folk paintings in this paper.In our study,we selected 15 kinds of representative red/blue pigments and dyes to test their Fourier transform infrared(FTIR)spectra,and then summarized the chemical structures and FTIR absorption features of these samples.Based on the standard spectra,we tested three traditional folk paintings printed in the late Qing Dynasty and early Republic of China using the attenuated total reflectance-Fourier transform infrared(ATR-FTIR)spectrometer.The results indicate that what were used on these paintings are synthetic pigments and dyes,including acid red G,methyl blue and Prussian blue.This work explores the application of FTIR technology in calligraphy and paintings,and provides a scientific basis for the nondestructive identification of pigments and dyes in traditional folk paintings.
作者 闫玥儿 张宇 段炼 刘鹏 唐颐 YAN Yue’er;ZHANG Yu;DUAN Lian;LIU Peng;TANG Yi(Institute for Preservation and Conservation of Chinese Ancient Books, Fudan University Library, Fudan University, Shanghai 200433, China;Shanghai History Museum, Shanghai 200003, China;History Institute, Shanghai Academy of Social Sciences, Shanghai 200235, China;Department of Chemistry, Fudan University, Shanghai 200433, China)
出处 《文物保护与考古科学》 北大核心 2020年第4期89-96,共8页 Sciences of Conservation and Archaeology
基金 国家自然科学基金资助(21805042) 文化和旅游部文化行业标准化研究项目资助(WH/Y08-2018) 上海市科委扬帆计划资助(18YF1401400) 上海市哲学社会科学规划课题资助(2014BWY005)。
关键词 红外光谱 传统年画 无损分析 红蓝色料 FTIR spectrum Traditional folk paintings Nondestructive analysis Red/blue pigments and dyes
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