摘要
介绍了异丁烯齐聚反应机理和异丁烯齐聚反应产物的利用,重点介绍了可以替代混合C4馏分中异丁烯醚化生产MTBE的工艺、异丁烯选择性齐聚反应不同类型催化剂的性能比较等研究现状,从经济、技术和发展等方面对混合C4馏分中异丁烯选择性齐聚提出了建议。
The reaction mechanism of isobutylene oligomerization and the utilization of oligomeric products are introduced,with emphasis on the process that can replace the etherification process in which isobutylene in mixed C4 fractions is etherified to produce MTBE,and the comparison of the performance of different catalysts for selective oligomerization of isobutylene.The suggestions about selective oligomerization of isobutylene in mixed C4 fractions are given from economy,technology and development aspects.
作者
孙大海
陈小平
杜玉朋
任万忠
田晖
SUN Da-hai;CHEN Xiao-ping;DU Yu-peng;REN Wan-zhong;TIAN Hui(College of Chemistry&Chemical Engineering,Yantai University,Yantai 264005,China;Shandong Provincial Collaborative Innovation Center for Comprehensive Utilization of Light Hydrocarbon,Yantai 264005,China)
出处
《现代化工》
CAS
CSCD
北大核心
2020年第8期62-66,共5页
Modern Chemical Industry
基金
山东省自然科学基金项目(ZR2017QB006)
烟台市科技发展计划项目(2018XSCC038)。
关键词
混合C4
异丁烯
选择性齐聚
催化剂
齐聚产物
mixed C4 fractions
isobutylene
selective oligomerization
catalyst
oligomeric products