摘要
基于Aspen Plus软件的Gibbs自由能最小化法,建立了煤粉在气流床中的富氧气化模型,该模型预测气化温度、产气组分和产气热值,与试验结果吻合良好。利用Aspen Plus的灵敏度分析模块研究氧气体积分数对气化温度、气体组分、产气热值、气体产率、有效气产率、碳转化率、气化效率及煤气污染物的影响,结果表明:随着氧气体积分数的增加,气化温度逐渐升高,H2,CO和CO2含量逐渐增加,而N2的含量逐渐降低,气体产率逐渐降低,有效气产率逐渐增加,产气热值、碳转化率和气化效率逐渐升高。随着氧气体积分数的增加,粗煤气中H2S的质量浓度逐渐增加。
Based on the Gibbs free energy minimization method,an oxygen enriched gasification model of the pulverized coal in the entrained flow bed was established by using the software of Aspen Plus.The predicated gasification temperature,gas composition and gas calorific values were in good agreement with the experimental results.The sensitivity analysis module of Aspen Plus was used to investigate the effects of oxygen volume fraction on the gasification temperature,gas composition,calorific value,carbon conversion rate,gas yield,effective gas yield,gasification efficiency and gas pollutants.The results show that with increasing oxygen volume fraction,the gasification temperature and the content of H2,CO and CO2,the effective gas yield,the calorific value,the carbon conversion rate and the gasification efficiency increase,while the content of N2 and the gas yield decrease.With increasing oxygen volume fraction,the mass concentration of H2S,SO2 and COS in the crude gas increases gradually.
作者
郑志行
张家元
李谦
周浩宇
胡兵
ZHENG Zhihang;ZHANG Jiayuan;LI Qian;ZHOU Haoyu;HU Bing(College of Energy Science and Engineering, Central South University, 410083 Changsha, China;National Engineering Research Center of Sintering and Pelletizing Equipment System, Zhongye Changtian International Engineering Company Limited, 410205 Changsha, China)
出处
《煤炭转化》
CAS
CSCD
北大核心
2020年第5期46-52,共7页
Coal Conversion
基金
湖南省自然科学基金资助项目(2020JJ5994).
关键词
Aspen
Plus
富氧气化
灵敏度分析
气流床
污染物
Aspen Plus
oxygen-enriched gasification
sensitivity analysis
entrained flow bed
pollutant