异核金属配合物NaZn(NO2)6O3(C5H5N)的晶体合成及结构分析

Crystal Synthesis and Structure Analysis of the Heteronuclea Metal Complex NaZn(NO2)6O3(C5H5N)

通过“一锅法”合成了1个钠和锌的异核金属配合物。其晶体属三斜晶系,空间群P-31c,a=1.02815(9)nm,b=1.02815(9)nm,c=1.21093(11)nm,α=90°,β=90°,γ=120°,V=1.10857(17)nm3,R=0.0631,wR=0.1703。配合物在硝酸根配体的桥连作用形成了1个一维链状结构。

The heteronuclea metal complex NaZn(NO2)6O3(C5H5N)is synthesized by“One Pot method”.The complex belongs to triclinic system with space group P-31c,a=1.02815(9)nm,b=1.02815(9)nm,c=1.21093(11)nm,β=90°,V=1.10857(17)nm3,R=0.0631,wR=0.1703.The complex forms a one-dimensional chain struc⁃ture through the Oxygen atom of the nitrate ligand.