含半夹心结构铱、铑化合物的配位自组装及电化学性能研究

Self-assembly and Electrochemical Properties of Iridium and Rhodium Compounds With Half-Sandwich Structure

目的:文章主要选用了铱、铑Cp^*M(M=Ir,Rh)为金属角,并且与联咪唑进行自组装分n别得到[Cp^*2Rh2L1]:(Cl4)和[Cp^*IrL1]:(Cl2)(L1:联咪唑)两种金属有机化合物。结论:含有半夹心结构有机金属铱或铑的化合物在有机合成和电化学发光等方面具有较高的应用前景,有利于开展目标化合物的实际应用研究。

Objective:In this paper,iridium and rhodium Cp^*M(M=Ir,Rh)are selected as metal angles,and are self-assembled with biimidazole to obtain[Cp^*2Rh2L1]:(Cl4)and[Cp^*IrL1]:(Cl2)(L1:biimidazole).Conclusion:Compounds containing half-sandwich organometallic iridium or rhodium have a high application prospect in organic synthesis and electrochemical luminescence,which is conducive to the practical application research of target compounds.