摘要
多金属氧簇(POMs,又称多酸或多金属氧酸盐)是一类组成确定,结构易于调控,具有酸性、氧化还原性等优异特性的簇合物.POMs在催化、材料、能源及药学等领域呈现出良好的应用前景,已成为多学科相互交叉融合的研究热点.本文主要综述了本课题组及国内外相关课题组在POMs催化剂的结构设计及其催化作用研究新进展,主要内容包括POMs催化剂的结构设计、酸碱催化、氧化还原催化、光催化以及对CO2和有毒有害分子的转化催化特性,并对未来POMs催化化学发展趋势进行了展望.
Polyoxometalates (POMs) is a kind of metal-oxygen clusters with well-defined structures, controllable composition, and excellent properties including acidity, redox properties, etc. In recent years, POMs have shown potential application in the field of catalysis, materials, energy conversion and pharmaceuticals and become a hot interdisciplinary research area. This review focuses on the recent progress in the structure design of POMs and their catalytic properties, mainly including POM structure chemistry, acid-base catalysis, redox catalysis, photocatalysis, the catalytic conversion of CO2 and toxic molecules. In addition, the future development of POMs-based catalysis is prospected.
作者
黄现强
甄妮
迟瑛楠
胡长文
Xianqiang Huang;Ni Zhen;Yingnan Chi;Changwen Hu(Key Laboratory of Cluster Science of Ministry of Education,Beijing Key Laboratory of Photoelectronic/Electrophotonic,School of Chemistry and Chemical Engineering,Beijing Institute of Technology,Beijing 100081,China;Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology,School of Chemistry&Chemical Engineering,Liaocheng University,Liaocheng 252059,China)
出处
《中国科学：化学》
CAS
CSCD
北大核心
2020年第9期1064-1092,共29页
SCIENTIA SINICA Chimica
基金
国家自然科学基金(编号:21671019,21871026,21871125)
山东省自然科学基金(编号:ZR2019MB043)资助项目。
关键词
多金属氧簇
结构设计
酸催化
氧化催化
光催化
polyoxometalates
structure design
acid catalysis
oxidation catalysis
photocatalysis
