卤代烃与小分子弱相互作用研究进展

Research Advances of Weak Interactions Between Halogenated Hydrocarbons and Small Molecules

卤代烃与小分子的弱相互作用已经成为化学领域的一个重要研究热点。本文对近年饱和含氢卤代烃、饱和全卤代烃和不饱和卤代烃与含氧氮小分子之间的弱相互作用(主要包括氢键、卤键和lp(lone pair)…π作用)在实验光谱学上的研究进展进行了综述,并在分子水平上对这些弱相互作用的计算研究进行了阐述。这些已有的研究成果将有助于弱相互作用在化学、材料和生物等领域的进一步应用。

Weak interactions between halogenated hydrocarbons and small molecules have become a hot research area in chemistry field.This article demonstrated experimental spectrum advances for clusters of halogenated hydrocarbons with oxygen/nitrogen containing simple small molecules.The halogenated hydrocarbons includes saturated halogenated hydrocarbons with hydrogen atoms,saturated perhalogenated hydrocarbons and unsaturated halogenated hydrocarbons.As well,computational studies to explore the nature of this weak interaction at molecular level were included.These research advances will contribute to the development of its chemical,material and biological applications.