关于有机化合物中碳正离子构型的讨论

Discussion on carbocation configuration in organic compounds

介绍了烷基碳正离子、桥头碳正离子、非经典碳正离子、含苯基的碳正离子、乙烯基碳正离子、乙炔基碳正离子的构型,并根据pKR+值和氢负离子的亲合势对苄基正离子与叔丁基正离子的稳定性进行了讨论。

This paper introduces the alkyl carbocation,bridgehead carbocation,non-classical carbocation,benzene-containing carbocation,vinyl carbocation,acetylene-based carbocation,The stability of benzyl and t-butyl carbocationare discussed according to the affinity of hydrogen negative ions and pKR+.