摘要
Polycyclic aromatic hydrocarbons with zigzag peripheries are high perspective candidates for organic electronics.However,large fused acenes are still poorly studied due to the tedious synthesis.Herein we report a non-substituted fused bistetracene DBATT(2.3,8.9-dibenzanthanthrene)as the semiconductor on low-voltage-driven organic thin-film transistors.The systematic studies of thin-film growth on various self-assembled monolayer(SAM)modified gate dielectrics and the electrical performances were carried out.The sub-monolayer of the semiconductor film shows larger island domains on the alkyl chain SAM.This device exhibits the hole mobility of 0.011 cm2·V−1·s−1 with a current ratio of IonIIoff above 105.
基金
Funded by the Deutsche Forschungsgemeinschaft(DFG)—Projektnummer 182849149—SFB 953
the Cluster of Excellence“Engineering of Advanced Materials”(EAM)
the“Graduate School Molecular School”.B.Z.(201706060215)acknowledges the supporting in Germany from China Scholarship Council(CSC).D.L.thanks the Alexander von Humboldt Foundation and the Japan Society for the Promotion of Science(JSPS)for a fellowship.