阶段占空比对ZrH1.8表面微弧氧化陶瓷层性能的影响

Effect of Phase Duty Cycle on the Properties of ZrH1.8 Surface Micro-arc Oxidized Ceramic Layer

为了提高氢化锆表面微弧氧化陶瓷层的致密性及阻氢性能,采用恒压模式对氢化锆基体进行微弧氧化处理,在磷酸盐电解液体系下,研究阶段占空比分别为40%-50%-60%、50%-60%-40%和60%-50%-40%三种情况下陶瓷层的生长过程。利用扫描电子显微镜(SEM)、X射线衍射仪(XRD)、膜层测厚仪分析陶瓷层的形貌、相结构及厚度;通过真空脱氢实验评价不同阶段占空比模式下获得陶瓷层的阻氢性能。研究结果表明:不同阶段占空比模式下在ZrH1.8表面可制得厚度分别为162.6、175.9、158.7μm的氧化锆陶瓷层,且所制微弧氧化陶瓷层均由M-ZrO2、T-ZrO2以及Zr0.95Ce0.05O2三种物相组成,阶段占空比对陶瓷层物相组成无显著影响;阶段占空比为40%-50%-60%条件下,氢化锆表面所制陶瓷层厚度达到162.6μm,氢渗透降低因子(Permeation Reduction Factor,PRF)达到12.5,阻氢性能较佳。

To study the respective growths of micro-arc oxidation(MAO)ceramic coatings under three phase duty cycles of 40%-50%-60%,50%-60%-40%,and 60%-50%-40%,and to thereby improve the compactness and hydrogen permeation resistance of the MAO ceramic coatings on the surface of zirconium hydride,the zirconium hydride matrix went through MAO treatment under constant voltage in the phosphate electrolyte system.On the one hand,the morphology,phase structure,and thickness of the ceramic coatings were analyzed by using scanning electron microscope(SEM),X-ray diffractometer(XRD),and film thickness meter.On the other hand,the hydrogen permeation resistance of the ceramic coatings under the different phase duty cycle was obtained through a vacuum dehydrogenation experiment.The research results indicate that under three phase duty cycle,the accumulated thickness of zirconium oxide ceramic coatings on the surface of ZrH1.8 are 162.6,175.9,and 158.7μm,respectively;all of the produced MAO ceramic coatings consist of three phases,namely M-ZrO2,T-ZrO2,and Zr0.95Ce0.05O2.Phase duty cycle has no significant effect on the phase composition of ceramic coatings.Under the phase duty cycle of 40%-50%-60%,the ceramic coating achieves on the surface of zirconium hydride has the thickness of 162.6μm and the Permeation Reduction Factor(PRF)value of 12.5,indicating a relatively satisfactory hydrogen permeation resistance.