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SAPO-34和HZSM-5机械混合分子筛在甲醇制丙烯反应中的应用 被引量:1

Application of mechanically-mixed SAPO-34/HZSM-5 molecular sieves in methanol to propylene
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摘要 采用机械复合的方法制备不同比例SAPO-34和HZSM-5的混合分子筛。利用XRD、SEM、FT-IR、BET和NH3-TPD等手段对样品进行物性和酸性表征,并考察各分子筛催化剂在甲醇制烯烃(MTO)反应中的催化性能。结果表明,部分小颗粒的HZSM-5粘连附着于大颗粒的SAPO-34表面上;SAPO-34和HZSM-5机械混合可以调节催化剂的酸性和微介孔结构;机械混合分子筛在MTO反应中有较高的催化剂寿命和丙烯选择性;在MSZ-90%混合分子筛上,当反应20 h时,丙烯的选择性高达48.9%,丙烯/乙烯比为4.0。 Mixed molecular sieves composing of SAPO-34 and HZSM-5 under different ratios are prepared by mechanically mixing method,and their catalytic performance in methanol to olefins(MTO)reaction are investigated.These samples are characterized by various techniques such as XRD,SEM,FT-IR,BET and NH3-TPD.The results show that some small HZSM-5 particles adhere to the surface of SAPO-34 particles with a large size,the physical mixture of SAPO-34 and HZSM-5 can adjust the acidity and pore structure of the catalyst,which helps to improve the catalytic performance of the catalyst in the MTO process.Catalytic test results show that the mixed catalysts exhibit longer lifetime and excellent selectivity for propylene.After the reaction has carried out for 20 hours over MSZ-90%mixed molecular sieves,the selectivity of propylene reaches as high as 48.9%and the production ratio between propylene and ethylene ratio is 4.0.
作者 徐文鹏 苏蛟蛟 韩丽 徐军 XU Wen-peng;SU Jiao-jiao;HAN Li;XU Jun(School of Chemical Engineering,Zhengzhou University,Zhengzhou 450001,China)
出处 《现代化工》 CAS CSCD 北大核心 2020年第10期86-90,共5页 Modern Chemical Industry
基金 国家自然科学基金资助项目-NSFC-河南人才联合培养基金(U1204215)。
关键词 混合分子筛 机械复合 甲醇制丙烯 催化寿命 mixed molecular sieves mechanically mixing methanol to propylene catalytic lifetime
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