摘要
以水性油墨废水絮凝污泥、三聚氰胺和K2CO3为原料,采用煅烧法制备了K^+掺杂石墨相氮化碳污泥基复合材料(AC/K-CN),利用XRD、UV-Vis DRS、FTIR、XPS、BET、SEM和PL光谱对AC/K-CN的晶体结构、形貌和光电性能进行了表征。可见光照射下,将AC/K-CN用于光催化降解阳离子蓝X-GRRL。结果表明,AC/K-CN对阳离子蓝X-GRRL的光催化活性明显高于纯石墨相氮化碳(g-C3N4)或碳化污泥(AC),这归因于AC/K-CN有效的电子-空穴分离。与AC和纯g-C3N4相比,AC/K-CN在模拟日光下对质量浓度为20 mg/L的阳离子蓝X-GRRL的降解率分别提高了43.17%和46.76%。
K+doped graphitic phase carbon nitride sludge-based composite(AC/K-CN)was prepared by calcination method using flocculation sludge of water-based ink wastewater,melamine and potassium carbonate as raw materials.The crystal structure,morphology and photoelectric properties of the composite were characterized by XRD,UV-Vis DRS,FTIR,XPS,BET,SEM and PL.The composite was applied to remove cationic blue X-GRRL from aqueous solution under visible-light irradiation.The results showed that the photocatalytic activity of AC/K-CN on cationic blue X-GRRL was higher than that of pure graphite phase carbon nitride(g-C3N4)or carbonized sludge(AC),which is attributed to the effective electron-hole separation of the composite.Compared with AC and pure g-C3N4,AC/K-CN composite increased the degradation rate of cationic blue X-GRRL with a mass concentration of 20 mg/L by 43.17%and 46.76% under simulated sunlight.
作者
马立标
张宾
柳荣展
张颖
詹丽凡
MA Libiao;ZHANG Bin;LIU Rongzhan;ZHANG Ying;ZHAN Lifan(College of Textiles and Clothing,Qingdao University,Qingdao 266071,Shandong,China;Shandong Ecological Textile Collaborative Innovation Center,Qingdao 266071,Shandong,China)
出处
《精细化工》
EI
CAS
CSCD
北大核心
2020年第11期2255-2261,共7页
Fine Chemicals
基金
国家自然科学基金(51508285)
山东省重点研发计划(重大科技创新工程)项目(2019JZZY010507,2019JZZY020301)。