摘要
A novel copper(I) coordination polymer [C30 H18 Cu3 Cl3 N4]n was solvethermally synthesized with 1-(prop-2-en-1-yl)-2-{4-[1-(prop-2-en-1-yl)-1 H-1,3-benzodiazol-2-yl]phenyl}-1 H-1,3-benzodiazole as the flexible ligand. It crystalizes in orthorhombic system, space group Pbcn with a = 22.0890(7), b = 6.3626(2), c = 18.2480(6) ?, V = 2564.64(14) ?3 and Mr = 365.73. The compound characterized by elemental analysis, infrared spectroscopy and powder X-ray diffraction analysis displays a 2 D structure. The complex shows strong green luminescence at 506 nm and better property of electrochemical oxygen evolution.
基金
Supported by the National Natural Science Foundation of China (NSFC21671084)。
