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N-Heterocyclic Carbene Copper(Ⅰ)Complex Catalyzed Coupling of(Hetero)aryl Chlorides and Nitrogen Heterocycles:Highly Efficient Catalytic System

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摘要 of main observation and conclusion A highly efficient catalytic system for the N-arylation reactions of(hetero)aryl chlorides and nitrogen heterocycles with a copper(l)complex containing a 1,10-phenanthroline analogue N-heterocyclic carbene(NHC)has been reported.The complex was characterized by^lH NMR and^13C NMR spectroscopy and elemental analysis,and its structure was determined by single-crystal X-ray diffraction.The NHC-copper(l)complex was employed as pre-catalyst for Ullmann type N-arylation reactions of(hetero)aryl chlorides with various azoles.A variety of hindered and functionalized azoles and(hetero)aryl chlorides were transformed in good to excellent yields.
出处 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2020年第11期1252-1256,共5页 中国化学(英文版)
基金 This work was supported by the Natural Science Foundation of Tianjin(No.16JCYBJC19700) the National Natural Science Foundation of China(No.21771138).
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