可溶性多孔高分子的合成及应用研究进展

Recent Developments on Soluble Porous Organic Polymers: Synthesis and Applications

综述将着重介绍可溶性多孔高分子的合成策略及应用方面的最新研究进展。从扭曲构象单体构筑法、超支化聚合法以及限域空间聚合法等三方面对可溶性多孔高分子的合成研究进展进行了归纳,并总结可溶性多孔高分子在气体分离、多相催化新策略、能源等方面的最新应用进展。不断丰富可溶性多孔高分子材料的结构多样性、发展新颖聚合方法并拓展其新应用领域,是该领域的研究热点。

This review focused on the latest research progress in the design of novel structures,synthetic strategies and applications of SPOPs.The syntheses of SPOPs could be achieved by several ways,such as using contorted monomers,hyper-branched polymerization strategy,polymerization in confined space and so on.It’s worth mentioning that all the contorted monomers used for building up porous polymers have been summarized,and the corresponding novel structures of SPOPs have been collected in this review.The applications of SPOPs based on their specific structures have been developed,which included selective separation of gases,new strategies of heterogeneous catalysis and energy materials.By tuning the pore size,functional groups and membrane morphology carefully,the properties of SPOPs have exceeded those of traditional commercial polymers.It is predictable that,more attention will be attracted towards the research in the field of SPOPs in the near future,especially when the structural diversity development is concerned,as well as novel polymerizations towards them and expanding their new applications.And it will be the research hot topics in the field of porous materials.