摘要
有机硼化合物来源广泛,转化丰富多样,已经成为一种重要的有机合成中间体,被广泛地应用于医药、农药以及有机光电材料的合成中.烷基硼化合物作为一类重要的有机硼化合物,其合成以及转化研究具有重要意义.可见光近来在有机反应领域受到广泛关注.在可见光诱导下,四配位烷基硼化合物能发生单电子转移产生烷基自由基,从而进一步构建不同的化学键.综述了该研究领域的相关进展.
Organoboron compounds are valuable synthetic intermediates and widely used in the synthesis of medicine,pesticide and organic optoelectronic materials due to their extensive resouce and highly transformable ability.Among various organoboron compounds,the synthesis and transformation of alkylboron compounds have attracted much attention.As a sustainable and green energy,visible light shows an important effect in organic systhesis.Tetracoordinated alkylboron compounds could occur single electron transfer(SET)process to generate alkyl radical for further transformations.Herein,the recent advances in the photoinduced transformation of alkyl boron compounds are summarized.
作者
史敦发
王露
夏春谷
刘超
Shi Dunfa;Wang Lu;Xia Chungu;Liu Chao(State Key Laboratory for Oxo Synthesis and Selective Oxidation,Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou 730000;University of Chinese Academy of Sciences,Beijing 100049)
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2020年第11期3605-3619,M0006,共16页
Chinese Journal of Organic Chemistry
基金
国家自然科学基金(Nos.21673261,91745110,21872156)
江苏省自然科学基金(Nos.BK20190002,BK20181194)
中国科学院青年创新促进会(No.2018458)资助项目.
关键词
硼
光催化
自由基
单电子转移
boron
photocatalysis
radical
single electron transfer
