由均苯三(5-四氮唑)配体构筑的Zn^(Ⅱ)基配合物的结构及荧光性质研究

Tructure and Fiuorescence Properties of Zn^(Ⅱ)-based Compounds Constructed by 5,5′,5″-(1,3,5-henylene)Tris(1H-Tetrazole)

以均苯三(5-四氮唑)配体(H3btt)、六水氯化锌为原料,通过调控不同的比例和酸碱度,在相同温度水热反应条件下得到了一个结构新颖的配位化合物1。该配合物表现为(4.12^(2))三维网状拓扑结构。此外,还对合成的配合物在室温条件下的固态荧光性质做了初步研究。

In this paper,thenovel coordination compound was obtained under the hydrothermal reaction conditions at the same temperature with 5,5′,5″-(1,3,5-phenylene)tris(1H-tetrazole)(H3btt)and zinc chloride hexahydrate as raw materials by controlling different ratios and pH.The compoundexhibit a three-dimensional(4.12^(2))network topology.In addition,the solid-state fluorescence propertie of Compound has been preliminarily studied at room temperature.