摘要
The two-dimensional surfaces have been fueled by the infinite possibility they offe red fo r basic re search,and for novel technologies in nanoelectronics.To realize many of these promises,the effective strategies were to design and control their surface chemistry,which plays a vital role in determining the chemical and physical properties.Macrocyclic host-guest chemistry with the reversible noncovalent interactions between macrocyclic hosts and suitable guests can be readily used for constructing multifunctional surfaces.Macrocyclic pillararenes,possessed the unique structure,have attracted the attentions of researchers in recent years.This feature article covers the recent development of pillararene-based twodimensional inte rfaces,including the fabrication and function of the hybrid composite.The combination of pillararenes and materials platform exhibited the novel property because of the characte ristic of cavity of macrocyclic host and confined spaces of surfaces.We anticipate that this review will be helpful to the researchers working in the fields of supramolecular chemistry and materials science.
基金
the Start-up Funding from South-Central University for Nationalities(No.YZZ19005)
the National Key Research and Development Program of China(No.2018YFD0200102)
the National Natural Science Foundation of China(Nos.21911530178 and 21772055)
the 111 Project(No.B17019)
self-determined research funds of CCNU from the colleges’basic research and operation of MOE
the Open Project of Hubei Key Laboratory of Wudang Local Chinese Medicine Research(Hubei University of Medicine)(No.WDCM2019003)。
