基于MOFs的衍生物及其电催化析氧性能的研究

Metal-organic Frameworks-based Catalyst for Oxygen Evolution Reaction

析氧反应(OER)在电化学水裂解中扮演着重要的角色,为可持续生产氢能提供更可行的途径。以金属有机框架(MOFs)作为模板所得到的衍生物具有可调控的结构/成分、高表面积以及有序孔道结构等优点。综述了近年来MOFs基衍生物在OER应用中的研究进展,所展示的实例将为制备高活性MOFs基衍生物提供参考。最后,展望了MOF基电催化剂工程化所面临的挑战和前景。

Oxygen evolution reaction(OER) plays an important role in electrochemical hydrocracking, providing a more feasible way for sustainable hydrogen production. The derivatives derived from metal organic framework(MOFs) have the advantages of controllable structure/composition, high surface area and ordered pore structure. In this paper, the research progress of MOFs-based derivatives in OER applications in recent years was reviewed. The examples presented can provide some reference for the preparation of highly active MOFs-based derivatives. Finally, the challenges and prospects of the engineering of MOF-based electrocatalysts were prospected.