摘要
近年来,金属有机骨架材料以其独特的结构及在多个领域的应用得到了人们的广泛关注,其中沸石咪唑酯类骨架材料(ZIF材料)是一类有特殊结构的有机金属骨架材料,多在较高的温度下合成,且具有较好的热稳定性。在室温条件下合成常见的ZIF材料(ZIF-8、ZIF-67、ZIF-90、ZIF-L)不仅可以减少环境污染,同时对ZIF材料的大规模生产应用具有很大的帮助。与此同时,在氮气氛围下对合成的ZIF材料在900℃下进行充分的热解,得到以ZIF材料为模板的衍生碳材料。
Metal-organic framework(MOF)material has attracted great attention because of its unique structures and various applications in many fields in recent years,and zeolite imidazolate framework(ZIF)is a special one of many kinds of MOF.ZIF is mainly synthesized at a pretty high temperature and possess better thermal stability.The synthesis of common ZIF materials(ZIF-8,ZIF-67,ZIF-90,ZIF-L)at room temperature can not only reduce environmental pollution,but also be of great help to the mass production and application of ZIF materials.At the same time,the synthesized ZIF was sufficiently pyrolyzed at 900℃under the atmosphere of nitrogen,and the derived carbon material using ZIF materials as template was obtained.
作者
程远
李志达
吴红军
Cheng Yuan;Li Zhida;Wu Hongjun(Chemistry and Chemical Engineering School of North Eastern Petroleum University,Daqing 163318)
出处
《化工新型材料》
CAS
CSCD
北大核心
2021年第1期90-94,98,共6页
New Chemical Materials
基金
国家自然科学基金(21476046)
黑龙江省杰出青年科学基金项目(JC2017002)
东北石油大学科研项目(GLJHB201901)。
关键词
沸石咪唑酯类骨架材料
室温合成
热解
碳材料
zeolite imidazolate framework
room-temperature synthesis
pyrolysis
carbon material
