摘要
(S,S)-Me-BI-DIME/Pd(0)-catalyzed ennantioselective C-H functionalization of N-ferrocenyl o-bromobenzanilides has been realized,affording isoquinolinone-fused ferrocenes with up to 97% ee.The products can be transformed into planar chiral ferrocenyl monophosphines,which demonstrate their preliminary application.
基金
the financial support from the National Natural Science Foundation of China(Nos.21572126,21202095,14HASTIT016)
Technicians Troop Construction Projects of Henan Province(No.C20150030)
Program of Science and Technology Innovation Talents of Henan Province(No.184100510011)。
