摘要
Potassium-ion batteries(PIBs) are promising scalable energy storage system;however,one of the challenges for its potential application is the huge volume variations during cycling due to the insertion/extraction of large size potassium ions.Here,we fabricated the S-doped carbon-coated rod-like FeS2/C@C,which not only effectively alleviate the volume variations upon cycling but also can improve electrical conductivity and maintain the structural integrity.As an anode material for PIBs,the rod-like FeS2/C@C electrodes delivered excellent rate performance(175 mA h g-1 at 0.5 A g-1) and stable cycle performance(262 mA h g-1 after 100 cycles at 0.1 A g-1).The superior excellent performance is associated with the unique structure of FeS2/C@C.The as-synthesized FeS2/C@C is demonstrated to be a potential anode for PIBs.
基金
supported by the National Natural Science Foundation of China(Nos.51302079,51702138)
the Natural Science Foundation of Hunan Province(No.2017JJ1008)
the Key Research and Development Program of Hunan Province of China(No.2018GK2031)。