金属有机骨架材料MOFs的结构及合成研究

Study on Structure and Synthesis of Metal-Organic Frameworks

近年来,金属有机骨架材料(MOFs)作为一种备受瞩目的新型三维结构多孔材料,因其具有特殊的多孔性、大比表面积、不饱和金属配位性及结构多样性等优势,在化工、环保等领域应用广泛。本文围绕MOFs材料的制备,重点介绍了模板剂法、缺陷位法、溶胶凝胶法及超临界CO_(2)法等合成方法,并对存在及需解决的问题进行了总结和展望。

In recent years,as a new type of three-dimensional porous materials,metal-organic frameworks(MOFs)attracted much attention.Because of their special porosity,large specific surface area,unsaturated metal coordination and structural diversity,MOFS were widely used in chemical industry,environmental protection and other fields.Focused on the preparation of MOFs materials,the template synthesis method,defect location method,sol-gel method and supercritical CO_(2) method were mainly introduced.The problems that existed and needed to be solved were summarized and prospected.