摘要
Two new complexes[Cu(AQTC)_(0.5)(H_(2)O)_(3)]·3H_(2)O}_(n) (1,H_(4)AQTC=anthraquinone-1,4,5,8-tetracarboxylic acid) and Cu[(Py)_(2)C(OH)_(2)]_(2)(H_(2)AQTC)·2H_(2)O (2,(Py)_(2)CO=di-2-pyridyl ketone) have been prepared and characterized by elemental analyses and IR spectroscopy.X-ray crystallographic studies show that complex 1crystallizes in monoclinic space group C2/m and complex 2 in monoclinic space group P2_1/c.Complex 1 features a1D chain structure by carboxyl oxygen atoms.Complex 2 displays a mononuclear structure and anions and cations are separated.What's interesting is that the ligand of H_(4)AQTC with eight carboxyl oxygen atoms and two quinone oxygen atoms does not directly coordinate with metals,and only exist as a counter-anion in complex 2.Three-dimensional structures of two complexes are formed by intermolecular interactions.The thermogravimetric analyses of two complexes are investigated.The luminescent properties of complex 1 are investigated as well.
作者
闫卫红
曾宪彩
YAN Wei-Hong;ZENG Xian-Cai(School of Biology and Chemical Engineering,Nanyang Institute of Technology,Henan Key Laboratory of Industrial Microbial Resources and Fermentation Technology,Nanyang 473004,China)
基金
Supported by the Scientific and Technological Research Projects of Henan Province(182102311077)
National Natural Science Foundation of China(21776063 and U1704127)。
