摘要
为了设计合理的转炉渣成分以达到满意的脱磷效果,根据转炉炼钢过程熔渣成分的变化范围,采用拉曼光谱测定了CaO-SiO 2-Fe x O-P 2O 5系熔渣的熔体结构,并解析了磷在熔渣中的存在形式及转变行为.结果表明,熔渣中磷主要以桥氧数为0,1,2的磷氧四面体结构单元存在,并可进入硅氧四面体和铁氧四面体形成Si—O—P和Fe—O—P键.随着渣中CaO和FeO总量的增加,熔渣中聚合程度较低的Q 0(P),Q 1(P)和Q 0(Si),Q 1(Si)摩尔分数升高,而聚合程度较高的Q 2(P)和Q 2(Si),Q 3(Si)摩尔分数降低.另外,Fe—O—P和Si—O—P键的含量也逐渐降低,当碱度为2.83时,Si—O—P和Fe—O—P键消失.
To design a reasonal composition of converter slag and achieve a satisfactory dephosphorization ratio,the structures of CaO-SiO 2-Fe x O-P 2O 5 molten slags were examined by Raman spectroscopy,and the existence form and transformation behavior of phosphorus were further analyzed in terms of the variation of slag composition during the process of basic oxygen steelmaking.The results show that phosphorus in molten slags mainly exists in the forms of Q 0(P),Q 1(P)and Q 2(P).Meanwhile,phosphorus can enter the silica tetrahedron and ferrite tetrahedron,and occupy the locations of silicon and iron to form the Si—O—P and Fe—O—P bonds,respectively.With the increasing total content of CaO and FeO,the molar fractions of the Q 0(P),Q 1(P),Q 0(Si)and Q 1(Si)with lower-degree polymerization increase,while the molar fractions of Q 2(P),Q 2(Si)and Q 3(Si)with higher-degree one decrease.In addition,Si—O—P and Fe—O—P bonds also gradually decrease.The Si—O—P and Fe—O—P bonds disappear,when the basicity of molten slag was 2.83.
作者
张蕊
贾吉祥
刘承军
闵义
ZHANG Rui;JIA Ji-xiang;LIU Cheng-jun;MIN Yi(Key Laboratory for Ecological Metallurgy of Multimetallic Mineral,Ministry of Education,Northeastern University,Shenyang 110819,China;School of Metallurgy,Northeastern University,Shenyang 110819,China;State Key Laboratory of Metal Material for Marine Equipment and Application,Anshan 114021,China.)
出处
《东北大学学报(自然科学版)》
EI
CAS
CSCD
北大核心
2021年第5期646-651,共6页
Journal of Northeastern University(Natural Science)
基金
国家重点研发计划项目(2017YFC0805100)
国家自然科学基金资助项目(51974075,51674069)
海洋装备用金属材料及其应用国家重点实验室开放基金资助项目(SKLMEA-K201911)
中央高校基本科研业务费专项资金资助项目(N182506001).
关键词
转炉渣
拉曼光谱
熔体结构
转变行为
磷
converter slag
Raman spectra
melt structure
transformation behavior
phosphorus