摘要
Carbon-based microassemblies(CMs) have attracted significant attention in numerous applications due to their unique hierarchical structures and delicate building blocks,especially when hollow carbon spheres(HCSs) are reasonably introduced into the construction.Herein,a new design for novel HCSscombined CMs is proposed.Remarkably,the HCSs are linear carbon bubbles linked one-by-one, arranging into necklaces decorating on the graphene microfolds.Detailed thermal analysis confirm that high temperatures straighten the linked carbon bubbles into bamboo-like carbon nanofibers,evidently due to the attenuation of doping degree.Benefiting from the abundant active sites of carbon bubbles,the obtained CMs exhibit satisfactory electrocatalytic activity for oxygen reduction reactions.This work establishes a bridge to precisely control the synthesis of carbon-based hierarchical architectures.
基金
financially supported by the National Key R&D Program of China(2017YFA0207201)
the National Natural Science Foundation of China(51872139,21905133,51902158)
the NSF of Jiangsu Province(BK20170045)
the Recruitment Program of Global Experts(1211019)
the “Six Talent Peak”Project of Jiangsu Province(XCL-043)
the Fundamental Research Funds for the Central Universities and the Recruitment Program of Global Experts(1211019,31020200QD041)
the Jiangsu Province Postdoctoral Science Foundation(2019K191)。