摘要
Lithium-sulfur(Li-S) battery is regarded as one of the most fascinating candidates for energy storage due to its dominant advantage of high energy density.However,the shuttling effect of soluble polysulfides and low electrical conductivity of sulfur and Li_(2)S still hinder its commercialization.In this work,high electrical-conductive carbon nanofibers(CNFs) with uniformly embedded polytungstates(HPW@CNFs) are proposed for advanced Li-S batteries.H_(3)PW_(12)O_(40)(HPW) is a kind of molecular nano-sized metal cluster which contains rich Lewis acid/base sites that can stabilize polysulfide effectively through chemical bonding,while CNFs play the role of physical barriers for polysulfides and transmission channel for electrons.The HPW@CNFs/S cathode shows an ultra-stable cycling performance with extremely small decay rate of 0.015% per cycle over 400 cycles at 0.5 C.
基金
financially supported by the National Natural Science Foundation of China(Grant No.51874360)
the Program of Huxiang Young Talents(Grant No.2019RS2002)
the Innovation-Driven Project of Central South University(2020CX027)
the Recruitment Program of Global Youth Experts。
