离子液体功能化环糊精化合物的合成及应用

Syntheses and Applications of Ionic Liquid Functionalized Cyclodextrin Compound

离子液体功能化环糊精化合物(ILs-CD)兼具环糊精"内疏水、外亲水"的结构特性和离子液体的低毒性、低蒸气压、电化学窗口宽、热稳定性和化学稳定性高等特性,是一类有巨大发展潜力的新型大环化合物。本文主要根据合成的ILs-CD化合物的阳离子不同对其进行了分类,并介绍了其合成方法,同时阐述了其在电化学、环境、食品、医药、催化、分子印迹、分离分析等不同领域的应用;并对ILs-CD化合物的未来发展方向进行展望,为ILs-CD化合物的制备和应用提供参考依据。

The ionic liquid functionalized cyclodextrin compound(ILs-CD)combines the"internally hydrophobic and externally hydrophilic"cavities of cyclodextrin and the low toxicity,low vapor pressure,wide electrochemical window,thermal stability and high chemical stability from ILs.So ILs-CD is a new type of macrocyclic compound with great development potential.This article mainly classifies the synthesized ILs-CD compounds ascording to their different cations,and introduces their synthesis methods.Meanwhile,the applications of ILs-CD in different fields such as in electrochemistry,environment,food,medicine,catalysis,molecular imprinting technology and separation analysis were elaborated.The current situation and development of ILs-CD were summarized.This will provide the help for the preparation and application of ILs-CD in the future.