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Catalytic combustion of vinyl chloride emissions over Co_(3)O_(4) catalysts with different crystallite sizes 被引量:1

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摘要 A series of Co_(3) O_(4) catalysts was prepared by ammonia(Co-AP) and oxalate(Co-OP) precipitation,solgel(Co-SG),and urea hydrothermal(Co-UH) methods,and their physicochemical properties were characterised by numerous techniques including X-ray diffraction(XRD),scanning electron microscopy(SEM),transmission electron microscopy(TEM),nitrogen sorption,X-ray photoelectron spectroscopy(XPS),temperature-programmed reduction of H_(2)(H_(2)-TPR),temperature-programmed desorption of O_(2)(O_(2)-TPD),and temperature-programmed desorption of NH_(3)(NH_(3)-TPD).The catalytic activity of each catalyst was estimated for the catalytic combustion of vinyl chloride(VC) emissions.The crystallite size of the Co_(3) O_(4) catalyst was found to be well correlated with the amounts of surface-adsorbed oxygen species and number of acid sites on the catalyst surface,and consequently,determined several physicochemical properties of the catalyst.Of the catalysts studied here,the Co-AP catalyst exhibits the smallest crystallite size,which increases the specific surface area and the concentration of Co^(2+) on the catalyst surface.This,in turn,enhances the redox property,oxygen mobility,and the number of acid sites associated with the Co-AP catalyst.In fact,the Co-AP catalyst exhibits the best catalytic activity for VC combustion at 360℃and does not produce any chlorinated by-products.
出处 《Rare Metals》 SCIE EI CAS CSCD 2021年第4期817-827,共11页 稀有金属(英文版)
基金 financially supported by the National Key Research and Development Program of China(No.2016YFC0204300) the National Natural Science Foundation of China(Nos.21922602 and 21577035) the Fundamental Research Funds for the Central Universities(No.222201717003)。
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