摘要
在氮杂环卡宾(NHC)/银(I)的共催化下,以芳醛和(溴乙炔)苯及其衍生物为原料实现了2-氧代-2-芳乙基芳甲酸酯高效合成.该方法具有底物范围广、原料简单易得、操作简便等优点,为α-酰氧基羰基衍生物的简捷合成提供了新思路.
An N-heterocyclic carbene(NHC)/Ag(I)co-catayzed efficient synthesis of 2-oxo-2-arylethyl aryl formates was realized by the reaction of aryl aldehydes with(bromoethynyl)benzenes.This method features broad substrate scope,ready availability of starting materials and operational simplicity,which gives an alternative access to α-acyloxycarbonyl derivatives.
作者
成立
王文蓉
孙玉倩
李团结
于晨侠
姚昌盛
Li Cheng;Wenrong Wang;Yuqian Sun;Tuanjie Li;Chenxia Yu;Changsheng Yao(Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials,School of Chemistry and Materials Science,Jiangsu Normal University,Xuzhou,Jiangsu 221116)
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2021年第4期1607-1613,共7页
Chinese Journal of Organic Chemistry
基金
国家自然科学基金(Nos.2177020721,21871113)
江苏高等学校自然科学基金(No.17KJA150003)资助项目。
