摘要
Multi-functional nanofibers are playing an important role in the optical field,and are widely used in fluorescence indication,product anti-counterfeit identification and smart clothing.Nanofibers with photoluminescence and photochromic functions are already attracting more interest from researchers.In this work,based on electrospun technology,the modified-PMMA nanofibers[PMMA=poly(methyl methacrylate)]with photoluminescence and photochromic functions were prepared through the design of the sheath-core structure(SCNFs 1-4).Compared with other samples,SCNF-4 shows outstanding photoluminescence and photochromic functions.SCNF-4 can produce green light and its fluorescence intensity and fluorescence lifetime can reach 7144 a.u.and 1031.32µs,respectively.In photochromic functions,SCNF-4 can show purple in 1 min under the 365 nm ultraviolet light,and the color can be preserved for more than 4 h under the sunlight.When SCNF-4 is irradiated by far infrared light,the color of the samples can fade quickly in 40 s.Under the irradiation of ultraviolet light of different wavelengths,SCNF-4 can display multi-color fluorescence and achieve a reversible transition between white and purple.The design of the sheath-core structure realizes the complementarity of photoluminescence and photochromic functions of the electrospun modified-PMMA nanofibers,which is important to promote the wide application of multi-functional nanofibers in the optical field.
基金
This work was supported by the Application Fundamental of Tianjin,China(No.18JCZDJC38300).
